The midfielder returned to Dikwena on a three-year deal in July as a free agent after leaving Greek club AE Larissa.
However, the Bafana Bafana international missed his side's first two games of the season with an ankle injury sustained on international duty.
Masalesa, though, is now available for the clash with Matsatsantsa at Lucas Moripe Stadium on September 12.
"He has recovered from his injury and is ready to play," says Stars general manager Senzo Mazingiza.
The Rustenburg-based outfit are looking for their first points of the campaign following a 2-0 home loss to Maritzburg United and 3-1 defeat at Cape Town City.